Síntesis de un composito pollucita/ferrihidrita/hematita: pellets para la adsorción de fosfatos a partir de agua residual sintética
Article Sidebar
Main Article Content
Abstract
Due to the increase of water eutrophication, it is necessary to develop technologies aimed at the tertiary treatment of wastewater until reaching levels according to the different regulations worldwide. This is how this study presents relevant information on the application of a natural muscovite to obtain a composite that allows reducing the concentration of phosphate in aqueous solutions. In this way it has been possible to obtain a pollucite/ferrihydrite/hematite composite in the form of pellets as the main mineralogical phases. Thus, a wide variety of batch experimental tests were carried out to assess the effectiveness of phosphate adsorption by powdered muscovite (P1M2—Fe—Al) and pollucite/ferrihydrite/hematite composite (pellets). Adsorption took place by physical and chemical adsorption; Additionally, the phosphate fractionation tests allowed corroborating the adsorption mechanisms proposed by electrostatic attraction and by monodentate and bidentate complexation reactions. Furthermore, phosphate adsorption is viable under normal conditions of the treated wastewater, since the adsorbent does not require pH adjustment. The pellet adsorbent presented a relatively slow adsorption, since it seems that intraparticle diffusion is the main mechanism that governs phosphate adsorption. Thus, in two hours of adsorption it was possible to adsorb 50% of phosphate. The powdered adsorbent had a better adsorption compared to the pellets, since with calcination the porosity blocks the access channels for the union of the phosphate with the oxy hydroxide groups of iron and aluminum. The regeneration of the pellets was limited, so the possibility of the final disposal of this adsorbent as a soil improver was evidenced, providing nutrients for plant growth. Thus, the use of the pollucite/ferrihydrite/hematite composite can contribute to solving the problems linked to the high concentrations of nutrients in the treated wastewater and, on the other hand, to the recovery of phosphates that can be added to the soil.
Downloads
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Con la finalidad de contar con un tipo de licencia más abierta en el espectro que ofrece Creative Commons, a partir de diciembre de 2022 desde el número 27, AXIOMA asume la Licencia Creative Commons 4.0 de Reconocimiento-NoComercial-CompartirIgual 4.0(CC BY-NC-SA 4.0). Tanto el sitio web como los artículos en sus diferentes formatos, reflejan esta información.
Hasta el mes de noviembre de 2022 con el número 26, la revista AXIOMA asumió una Licencia Creative Commons Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0). Los artículos contenidos en cada número hasta el 26, cuentan con esta licencia y su descripción se conserva en el portal de nuestra revista.
Atribución-NoComercial-SinDerivadas
CC BY-NC-ND
AXIOMA- Revista Científica de Investigación, Docencia y Proyección Social
References
Albukhari, S. M., Salam, M. A., & Abukhadra, M. R. (2021). Effective retention of inorganic Selenium ions (Se (VI) and Se (IV)) using novel sodalite structures from muscovite; characterization and mechanism. Journal of the Taiwan Institute of Chemical Engineers, 120, 116–126. https://doi.org/https://doi.org/10.1016/j.jtice.2021.02.026
Awad, A. M., Shaikh, S. M. R., Jalab, R., Gulied, M. H., Nasser, M. S., Benamor, A., & Adham, S. (2019). Adsorption of organic pollutants by natural and modified clays: A comprehensive review. Separation and Purification Technology, 228, 115719. https://doi.org/https://doi.org/10.1016/j.seppur.2019.115719
Awual, Md. R., El-Safty, S. A., & Jyo, A. (2011). Removal of trace arsenic(V) and phosphate from water by a highly selective ligand exchange adsorbent. Journal of Environmental Sciences, 23(12), 1947–1954. https://doi.org/https://doi.org/10.1016/S1001-0742(10)60645-6
Bacelo, H., Pintor, A. M. A., Santos, S. C. R., Boaventura, R. A. R., & Botelho, C. M. S. (2020). Performance and prospects of different adsorbents for phosphorus uptake and recovery from water. Chemical Engineering Journal, 381, 122566. https://doi.org/https://doi.org/10.1016/j.cej.2019.122566
Buzetzky, D., Nagy, N. M., & Kónya, J. (2017). Use of La-, Ce-, Y-, Fe- bentonites for removing phosphate ions from aqueous media. Periodica Polytechnica Chemical Engineering, 61(1), 27–32. https://doi.org/10.3311/PPch.9871
Eden, C. L., & Daramola, M. O. (2021). Evaluation of silica sodalite infused polysulfone mixed matrix membranes during H2/CO2 separation. Materials Today: Proceedings, 38, 522–527. https://doi.org/https://doi.org/10.1016/j.matpr.2020.02.393
Guaya, D., Cobos, H., Camacho, J., López, C. M., Valderrama, C., & Cortina, J. L. (2022). LTA and FAU-X Iron-Enriched Zeolites: Use for Phosphate Removal from Aqueous Medium. In Materials (Vol. 15, Issue 15). https://doi.org/10.3390/ma15155418
Guaya, D., Cobos, H., Valderrama, C., & Cortina, J. L. (2022). Effect of Mn2+/Zn2+/Fe3+ Oxy(Hydroxide) Nanoparticles Doping onto Mg-Al-LDH on the Phosphate Removal Capacity from Simulated Wastewater. In Nanomaterials (Vol. 12, Issue 20). https://doi.org/10.3390/nano12203680
Guaya, D., Jiménez, R., Sarango, J., Valderrama, C., & Cortina, J. L. (2021). Iron-doped natural clays: Low-cost inorganic adsorbents for phosphate recovering from simulated urban treated wastewater. Journal of Water Process Engineering, 43, 102274. https://doi.org/https://doi.org/10.1016/j.jwpe.2021.102274
Guaya, D., Maza, L., Angamarca, A., Mendoza, E., García, L., Valderrama, C., & Cortina, J. L. (2022). Fe3+/Mn2+ (Oxy)Hydroxide Nanoparticles Loaded onto Muscovite/Zeolite Composites (Powder, Pellets and Monoliths): Phosphate Carriers from Urban Wastewater to Soil. Nanomaterials, 12(21). https://doi.org/10.3390/nano12213848
Guaya, D., Valderrama, C., Farran, A., Armijos, C., & Cortina, J. L. (2015). Simultaneous phosphate and ammonium removal from aqueous solution by a hydrated aluminum oxide modified natural zeolite. Chemical Engineering Journal, 271, 204–213. https://doi.org/10.1016/j.cej.2015.03.003
Guaya, D., Valderrama, C., Farran, A., & Cortina, J. L. (2016a). Modification of a natural zeolite with Fe(III) for simultaneous phosphate and ammonium removal from aqueous solutions. Journal of Chemical Technology and Biotechnology, 91(6), 1737–1746. https://doi.org/10.1002/jctb.4763
Guaya, D., Valderrama, C., Farran, A., & Cortina, J. L. (2016b). Modification of a natural zeolite with Fe(III) for simultaneous phosphate and ammonium removal from aqueous solutions. Journal of Chemical Technology & Biotechnology, 91(6), 1737–1746. https://doi.org/https://doi.org/10.1002/jctb.4763
Guaya, D., Valderrama, C., Farran, A., & Cortina, J. L. (2017). Simultaneous nutrients (N,P) removal by using a hybrid inorganic sorbent impregnated with hydrated manganese oxide. Journal of Environmental Chemical Engineering, 5(2), 1516–1525. https://doi.org/10.1016/j.jece.2017.02.030
Hosseini, S., Moghaddas, H., Masoudi Soltani, S., & Kheawhom, S. (2020). Technological Applications of Honeycomb Monoliths in Environmental Processes: A review. Process Safety and Environmental Protection, 133, 286–300. https://doi.org/https://doi.org/10.1016/j.psep.2019.11.020
Karimi, L., & Salem, a. (2011). The role of bentonite particle size distribution on kinetic of cation exchange capacity. Journal of Industrial and Engineering Chemistry, 17(1), 90–95. https://doi.org/10.1016/j.jiec.2010.12.002
Khan, F., & Ansari, A. A. (2005). Eutrophication: an ecological vision. The Botanical Review, 71(4), 449–482.
Kumar, M. M., & Jena, H. (2022). Direct single-step synthesis of phase pure zeolite Na–P1, hydroxy sodalite and analcime from coal fly ash and assessment of their Cs+ and Sr2+ removal efficiencies. Microporous and Mesoporous Materials, 333, 111738. https://doi.org/https://doi.org/10.1016/j.micromeso.2022.111738
Liang, X., Zang, Y., Xu, Y., Tan, X., Hou, W., Wang, L., & Sun, Y. (2013). Sorption of metal cations on layered double hydroxides. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 433, 122–131. https://doi.org/https://doi.org/10.1016/j.colsurfa.2013.05.006
M.H. McCrady. American Journal of Public Health and the Nations Health. (2011). Standard methods for the examination of water and wastewater (12th ed.).
Moharami, S., & Jalali, M. (2013a). Removal of phosphorus from aqueous solution by Iranian natural adsorbents. Chemical Engineering Journal, 223, 328–339. https://doi.org/https://doi.org/10.1016/j.cej.2013.02.114
Moharami, S., & Jalali, M. (2013b). Removal of phosphorus from aqueous solution by Iranian natural adsorbents. Chemical Engineering Journal, 223, 328–339. https://doi.org/10.1016/j.cej.2013.02.114
Reitzel, K., Andersen, F. Ø., Egemose, S., & Jensen, H. S. (2013). Phosphate adsorption by lanthanum modified bentonite clay in fresh and brackish water. Water Research, 47(8), 2787–2796. https://doi.org/https://doi.org/10.1016/j.watres.2013.02.051
Robben, L., & Gesing, T. M. (2013). Temperature-dependent framework–template interaction of |Na6(H2O)8|[ZnPO4]6 sodalite. Journal of Solid State Chemistry, 207, 13–20. https://doi.org/https://doi.org/10.1016/j.jssc.2013.08.022
Shanableh, A. M., & Elsergany, M. M. (2013). Removal of phosphate from water using six Al-, Fe-, and Al-Fe-modified bentonite adsorbents. Journal of Environmental Science and Health, Part A, 48(2), 223–231. https://doi.org/10.1080/10934529.2012.717820
Valderrama, C., Barios, J. I., Caetano, M., Farran, A., & Cortina, J. L. (2010). Kinetic evaluation of phenol/aniline mixtures adsorption from aqueous solutions onto activated carbon and hypercrosslinked polymeric resin (MN200). Reactive and Functional Polymers, 70(3), 142–150. https://doi.org/https://doi.org/10.1016/j.reactfunctpolym.2009.11.003
Verstraete, W., Van de Caveye, P., & Diamantis, V. (2009). Maximum use of resources present in domestic “used water.” Bioresource Technology, 100(23), 5537–5545. https://doi.org/https://doi.org/10.1016/j.biortech.2009.05.047
Weber, W.J. and Morris, J. C. (1963). No TitleKinetics of adsorption carbon from solutions. Journal Sanitary Engeering Division Proceedings.American Society of Civil Engineers, 89, 31–60.
Yeoman, S., Stephenson, T., Lester, J. N., & Perry, R. (1988). The removal of phosphorus during wastewater treatment: A review. Environmental Pollution, 49(3), 183–233. https://doi.org/10.1016/0269-7491(88)90209-6
Yin, H., Yang, C., Jia, Y., Chen, H., & Gu, X. (2018). Dual removal of phosphate and ammonium from high concentrations of aquaculture wastewaters using an efficient two-stage infiltration system. Science of the Total Environment, 635, 936–946. https://doi.org/10.1016/j.scitotenv.2018.04.218
Zamparas, M., Gianni, A., Stathi, P., Deligiannakis, Y., & Zacharias, I. (2012). Removal of phosphate from natural waters using innovative modified bentonites. Applied Clay Science, 62–63, 101–106. https://doi.org/10.1016/j.clay.2012.04.020